Publications

Year

2023
2022
2021
2020
2019
2018
2017
2016
2015
2014
2013
2012
2010
2009
All Years

2023

Selective Electrochemical Reductive Amination of Benzaldehyde at Heterogeneous Metal Surfaces
Zachary J. Schiffer, Minju Chung, Katherine Steinberg, Karthish Manthiram Chem Catalysis 3, (2023)
Toward Improving the Selectivity of Organic Halide Electrocarboxylation with Mechanistically Informed Solvent Selection
Nathan Corbin, Glen P. Junor, Thu N. Ton, Rachel J. Baker, Karthish Manthiram J. Am. Chem. Soc. , (2023)

2022

Imaging nitrogen fixation at lithium solid electrolyte interphases via cryo-electron microscopy
Katherine Steinberg, Xintong Yuan, Nikifar Lazouski, Channing K. Klein, Karthish Manthiram, Yuzhang Li Nat Energy , (2022)
Sustainable ammonia synthesis: Just around the corner?
Channing K. Klein, Karthish Manthiram Joule 6, 1971-1973 (2022)
Tuning Single-Atom Dopants on Manganese Oxide for Selective Electrocatalytic Cyclooctene Epoxidation
Minju Chung, Kyoungsuk Jin, Joy S. Zeng, Thu N. Ton, Karthish Manthiram J. Am. Chem. Soc. 144, 17416-17422 (2022)
Ammonium Formate as a Safe, Energy-Dense Electrochemical Fuel Ionic Liquid
Zachary J. Schiffer, Sayandeep Biswas, Karthish Manthiram ACS Energy Lett. 7, 3260-3267 (2022)
Cost and Performance Targets for Fully Electrochemical Ammonia Production under Flexible Operation
Nikifar Lazouski, Aditya Limaye, Abhishek Bose, Michal L. Gala, Karthish Manthiram, and Dharik S. Mallapragada ACS Energy Lett. 7, 2627-2633 (2022)
Spatial Variation in Cost of Electricity-Driven Continuous Ammonia Production in the United States
Abhishek Bose, Nikifar Lazouski, Michal L. Gala, Karthish Manthiram, Dharik S. Mallapragada ACS Sustainable Chem. Eng. 10, 7862-7872 (2022)
Proton Donors Induce a Differential Transport Effect for Selectivity toward Ammonia in Lithium-Mediated Nitrogen Reduction
Nikifar Lazouski, Katherine J. Steinberg, Michal L. Gala, Dilip Krishnamurthy, Venkatasubramanian Viswanathan, Karthish Manthiram ACS Catalysis 12, 5197-5208 (2022)
Accounting for species’ thermodynamic activities changes mechanistic interpretations of electrochemical kinetic data
Kindle Williams, Aditya Limaye, Trent Weiss, Minju Chung, Karthish Manthiram ChemRxiv , (2022)

2021

NGenE 2021: Electrochemistry Is Everywhere
Jordi Cabana, Thomas Alaan, George W. Crabtree, Marta C. Hatzell, Karthish Manthiram, Daniel A. Steingart, Iryna Zenyuk, Feng Jiao, Aleksandra Vojvodic, Jenny Y. Yang, Nitash P. Balsara, Kristin A. Persson, Donald J. Siegel, Christy L. Haynes, Janine Mauzeroll, Mei Shen, B. Jill Venton, Nina Balke, Joaquín Rodríguez-López, Debra R. Rolison, Reza Shahbazian-Yassar, Venkat Srinivasan, Santanu Chaudhuri, Adrien Couet, Jason Hattrick-Simpers ACS Energy Lett. 7, 368-374 (2021)
Closed-Loop Electrolyte Design for Lithium-Mediated Ammonia Synthesis
Dilip Krishnamurthy, Nikifar Lazouski, Michal L. Gala, Karthish Manthiram, Venkatasubramanian Viswanathan ACS Central Science 7, 2073-2082 (2021)
Suppressing Carboxylate Nucleophilicity with Inorganic Salts Enables Selective Electrocarboxylation without Sacrificial Anodes
Nathan Corbin, Dengtao Yang, Nikifar Lazouski, Katherine Steinberg, Karthish Manthiram Chemical Science 12, 12365-12376 (2021)
Probing metal-organic frameworks during water oxidation electrocatalysis
Minju Chung, Karthish Manthiram Matter 4, 2593-2595 (2021)
Electrochemical Modulation of Carbon Monoxide-Mediated Cell Signaling
Jimin Park, Joy S. Zeng, Atharva Sahasrabudhe, Kyoungsuk Jin, Yoel Fink, Karthish Manthiram, Polina Anikeeva Angewandte Chemie International Edition , (2021)
Bayesian Data Analysis Reveals No Preference for Cardinal Tafel Slopes in CO₂ Reduction Electrocatalysis
A. M. Limaye, J. S. Zeng, A. Willard, K. Manthiram Nature Communications 12, 703 (2021)
Thermodynamic Discrimination between Energy Sources for Chemical Reactions
Z. J. Schiffer, A. M. Limaye, K. Manthiram Joule 5, 135-148 (2021)
Redox Reservoirs: Enabling More Modular Electrochemical Synthesis
J. S. Zeng and K. Manthiram Trends in Chemistry 3, 3 (2021)

2020

Mechanism of Chlorine-mediated Electrochemical Ethylene Oxidation in Saline Water
M. Chung, K. Jin, J. S. Zeng, K. Manthiram ACS Catalysis 10, 14015-14023 (2020)
In situ electrochemical generation of nitric oxide for neuronal modulation
J. Park, K. Jin, A. Sahasrabudhe, P. Chiang, J. H. Maalouf, F. Koehler, D. Rosenfeld, S. Rao, T. Tanaka, T. Khudiyev, Z. J. Schiffer, Y. Fink, O. Yizhar, K. Manthiram, and P. Anikeeva Nature Nanotechnology 15, 690-697 (2020) Highlighted in Nature Nanotechnology by K. T. Nam and S. Park,MIT News by D. L. Chandler
Non-aqueous gas diffusion electrodes for rapid ammonia synthesis from nitrogen and water-splitting-derived hydrogen
N. Lazouski, M. Chung, K. Williams, M. L. Gala, and K. Manthiram Nature Catalysis 3, 463-469 (2020) Highlighted in Science by R. Service,MIT News by A. Trafton,RSC Chemistry World by T. Wogan,The Chemical Engineer by A. Doyle,Nature Catalysis ,by C. Ampelli
Kinetic Analysis of Electrochemical Lactonization of Ketones Using Water as the Oxygen Atom Source
J. H. Maalouf, K. Jin, D. Yang, A. Limaye, and K. Manthiram ACS Catalysis 10, 5750-5756 (2020)
Kinetic Analysis on the Role of Bicarbonate in Carbon Dioxide Electroreduction at Immobilized Cobalt Phthalocyanine
J. S. Zeng, N. Corbin, K. Williams, and K. Manthiram ACS Catalysis 10, 4326-4336 (2020)

2019

Heterogeneous molecular catalysts for electrocatalytic CO₂ reduction
N. Corbin, J. Zeng, K. Williams, K. Manthiram Nano Research 12, 2093-2125 (2019) Highlighted in Nano Research Young Innovators Awards (NR45)
Direct electrochemical carboxylation of benzylic C-N bonds with carbon dioxide
D. Yang, M. Zhu, Z. J. Schiffer, K. Williams, X. Song, X. Liu, K. Manthiram ACS Catalysis 9, 4699-4705 (2019)
Epoxidation of Cyclooctene Using Water as the Oxygen Atom Source at Manganese Oxide Electrocatalysts
K. Jin, J. H. Maalouf, N. Lazouski, N. Corbin, D. Yang, and K. Manthiram Journal of the American Chemical Society 141, 6413-6418 (2019) Highlighted in The Chemical Engineer by A. Jasi,MIT News by A. Trafton,C&EN by L. Boerner,Energy Futures by N. Stauffer,C&EN Year in Review
Nature of the first electron transfer in electrochemical ammonia activation in a non-aqueous medium
Z. Schiffer, N. Lazouski, N. Corbin, and K. Manthiram Journal of Physical Chemistry C 123, 9713-9720 (2019)
Protecting Effect of Mass Transport during Electrochemical Reduction of Oxygenated Carbon Dioxide Feedstocks
K. Williams, N. Corbin, J. Zeng, N. Lazouski, D. Yang, and K. Manthiram Sustainable Energy & Fuels 3, 1225-1232 (2019)
Ambient lithium-mediated ammonia synthesis
N. Lazouski and K. Manthiram Trends in Chemistry 1, 141-142 (2019)
Understanding Continuous Lithium-Mediated Electrochemical Nitrogen Reduction
N. Lazouski, Z. J Schiffer, K. Williams, and K. Manthiram Joule 3, 1-13 (2019) Highlighted in Joule by Maheshwari and Janik
Inductive and electrostatic effects on immobilized cobalt porphyrins for electrocatalytic CO₂ reduction
M. Zhu, D. Yang, R. Ye, J. Zeng, N. Corbin, and K. Manthiram Catalysis Science and Technology 9, 974-980 (2019)

2018

Elucidating Reactivity and Mechanism of CO2 Electroreduction at Highly Dispersed Cobalt Phthalocyanine
M. Zhu, R. Ye, K. Jin, N. Lazouski, and K. Manthiram ACS Energy Letters 3, 1381-1386 (2018)

2017

Electrification and Decarbonization of the Chemical Industry
Z. J. Schiffer and K. Manthiram Joule 1, 10-14 (2017)

2016

Study of Heat Transfer Dynamics from Gold Nanorods to the Environment via Time-Resolved Infrared Spectroscopy
S. Nguyen, Q. Zhang, K. Manthiram, X. Ye, J. P. Lomont, C. B. Harris, H. Weller, and A. P. Alivisatos ACS Nano 10, 2144-2151 (2016)

2015

In Situ Transmission Electron Microscopy of Cadmium Selenide Nanorod Sublimation
D. Hellebusch, K. Manthiram, B. J. Beberwyck, and A. P. Alivisatos Journal of Physical Chemistry Letters 6, 605-611 (2015)
Interaction potentials of anisotropic nanocrystals from the trajectory sampling of particle motion in in-situ liquid phase transmission electron microscopy
Q. Chen, H. Cho, K. Manthiram, M. Yoshida, X. Ye, and A. P. Alivisatos ACS Central Science 1, 33-39 (2015)
Chemical Controls of Plasmons in Metal Chalcogenide and Metal Oxide Nanostructures
T. M. Mattox, X. Ye, K. Manthiram, A. P. Alivisatos, and J. J. Urban Advanced Materials 27, 5380-5837 (2015)

2014

Dendritic assembly of gold nanoparticles during fuel-forming electrocatalysis
K. Manthiram, Y. Surendranath, and A. P. Alivisatos Journal of the American Chemical Society 136, 7237-7240 (2014)
Enhanced electrochemical methanation of carbon dioxide with a dispersible nanoscale copper catalyst
K. Manthiram, B. J. Beberwyck, and A. P. Alivisatos Journal of the American Chemical Society 136, 13319-13325 (2014)

2013

Seeded Synthesis of CdSe/CdS Rod and Tetrapod Nanocrystals
K. Manthiram,* B. J. Beberwyck,* D. V. Talapin, and A. P. Alivisatos Journal of Visualized Experiments 82, 50731 (2013)
Doped Nanocrystals as Plasmonic Probes of Redox Chemistry
P. K. Jain, K. Manthiram, J. Engel, S. L. White, J. A. Faucheaux, and A. P. Alivisatos Angewandte Chemie International Edition 52, 13671-13675 (2013)

2012

Tunable Localized Surface Plasmon Resonances in Tungsten Oxide Nanocrystals
K. Manthiram and A. P. Alivisatos Journal of the American Chemical Society 134, 3995-3998 (2012)

2010

Comparing the functional properties of the Hsp70 chaperones, DnaK and BiP
J. Bonomo, J. P. Welsh, K. Manthiram, and J. R. Swartz Biophysical Chemistry 149, 58-66 (2010)

2009

Multiply Mutated Gaussia Luciferases Provide Prolonged and Intense Bioluminescence
J. P. Welsh, K. G. Patel, K. Manthiram, and J. R. Swartz Biochemical and Biophysical Research Communications 389, 563-568 (2009)

CALIFORNIA INSTITUTE OF TECHNOLOGY

Division of Chemistry and Chemical Engineering

Karthish (PI): 626-395-3140 / karthish@caltech.edu / Spalding 225

Martha (Admin): 626-395-2423 / martha@cheme.caltech.edu / Spalding 208

Caltech | Division of Chemistry and Chemical Engineering